TCB Publications - Abstract

Robert Bittl and Klaus Schulten. Length dependence of the magnetic field modulated triplet yield of photogenerated biradicals. Chemical Physics Letters, 146:58-62, 1988.

BITT88 The magnetic field dependence of the triplet yield of biradicals of the type $^{2}A^{+}-(CH_{2})n^{-2}D^{-}$ has been calculated for three different lengths n=8,9, and 10 of the linking aliphatic chain. The calculations are based on the solution of the stochastic Liouville equation under the assumption of a "through space" exchange interaction and compare well with experimental observations. We show that the field dependence of the triplet yield is governed by the "spectrum of the exchange interaction".

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